高能硝胺推进剂的压强指数分析

从高能硝胺推进剂配方组成入手 ,深入研究了各组分参数的变化对该推进剂燃烧性能的影响 ,认为 :高硝胺 ( HMX或 RDX)含量和高硝酸酯增塑剂含量是高能硝胺推进剂 ( NEPE)高压强指数的根本原因。同时指出该类推进剂的燃烧性能的调节将不再仅仅局限于硝胺的催化 ,而应针对硝胺和硝酸酯及 AP的特殊作用进行综合调节     

Nitrogen analogs of TEX – A computational study

TEX, a well-known nitramine type explosive, has been subjected to centric perturbations by replacing its etheric (acetal) oxygens with nitrogen atoms one by one. The structural features, stabilities and IR and UV-VIS spectra of new structures formed are investigated. For this purpose, density functional theory has been employed at the B3LYP/6-31G (d,p) and B3LYP/6-311G(d) levels. In general the calculations revealed that the oxygen–nitrogen replacement resulted in more energetic but less sensitive structures than TEX.     

JTIDS消息字还原模块的FPGA设计

根据公开的关于Link16数据链的信息标准并结合我军对战术数据链的具体要求,设计了一种JTIDS终端消息字还原模块,该模块包含CCSK码字解密,CCSK译码,解交织,RS译码等一系列基带数据处理过程。首先介绍了Link16数据链消息字还原模块的原理,对其各个子处理模块进行了设计并提出了硬件实现方案,然后在Quartus II环境下选择Cyclone II系列的EP2C8Q208C8 FPGA芯片进行了JTIDS消息字还原模块的系统级综合与仿真,并在该芯片的开发板上进行了验证,硬件成品可用于JTIDS终端功能测试与评估等多种场合。     

Preparation of reduced sensitivity co-crystals of cyclic nitramines using spray flash evaporation

The present day weapon technology demands novel energetic materials that exhibit simultaneous high explosive yield and reduced sensitivity. This article demonstrates application of spray evaporation to prepare reduced sensitive co-crystals of high performance nitramine explosives like HMX and CL-20 with a relatively less insensitive explosive 1,1-diamino-2,2-dinitroethylene or FOX-7. Stronger intermolecular hydrogen bonding in FOX-7 is responsible for limited solubility in most of organic solvents. Large solubility differences of FOX-7 with HMX and CL-20 restricts it's co-crystallization through classical methods that yields thermodynamically favorable product. Spray flash evaporation, a kinetic crystallization method, has been therefore adopted and could successfully produce CL-20/FOX-7 (2:1) and HMX/FOX-7 (4:1) co-crystals. The fine powdered materials obtained were characterized by SEM, powder XRD, Raman spectroscopy, DSC-TGA etc. Multipoint Raman spectra showed consistent occurrence of spectral features indicating stoichiometric co-existence of ingredients in the crystal lattices. DSC analysis showed absence of all thermally assisted solid-solid phase transformation in the co-crystals as they were observed in pristine materials. The thermal stability calculated in terms of activation barrier for decomposition, revealed the CL-20/FOX-7 co-crystal to be intermediately stable on comparison to their constituents while, the HMX/FOX-7 co-crystal is more stable. Compared to pure HMX and CL-20, both the co-crystals have shown higher insensitivity to impact force, suggesting them to be suitable for future generation insensitive munitions.     

Effects of jute fibre content on the mechanical and dynamic mechanical properties of the composites in structural applications

Due to notable characteristics, sustainability concept and environmental issues, hybridisation natural with synthetic fibres to fabricate composites have been rapidly gaining market share in different applications (structural, military, aerospace and automotive vehicles). Compression, tension and fatigue tests of various stacking sequences of plain jute/carbon reinforced (PVB) polyvinyl butyral by hot hydraulic press technique were experimentally conducted. Six types of fabricated composites with various constituents (jute, carbon and their hybrids) were fabricated and tested. Notably, fatigue lifetime of hybrids increases with increasing the carbon content relative to the jute fibre content. On the other hand, Jute composites possess high strain compared to pure carbon composite, which gives an overall improvement in mechanical behaviours. Interestingly, H1 hybrid with Carbon/Jute/Carbon sequences offers similar fatigue stiffness behaviour of H3 hybrid with Carbon/Jute/Carbon/Jute sequences when subjected to cyclic loading. Carbon composite (C) exhibited the highest fatigue resistance, whiles jute composite (J) possessed the highest strain and semi brittle trends in both mechanical and fatigue performance. Results concluded that plain jute fibres could partially replace high-cost synthetic carbon fibres to produce more eco-friendly hybrids to be utilised in different composites industries.